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monomers are examples of M and Ms, respectively; vinyl acetate and styrene radicals are examples of R and Rs , respectively. There are two sets of potential energy plots in Fig. 6-11. One set of four repulsion plots represents the energetics of the approach of a radical to a monomer; the other set of two Morse plots represents the stability of the bond (or of the polymer radical) nally formed. The intersections of the plots represent the transition states for the monomer-radical reactions (Eqs. 6-51a to 6-51d) where the unbonded and bonded states have the same energies. The various activation energies and heats of reaction are represented by the solid-line and broken-line arrows, respectively. The separation between the two Morse plots is signi cantly larger than that between either the top or bottom two repulsion plots, since substituents are much more effective in decreasing radical reactivity than in increasing monomer reactivity. Figure 6-11 shows that the order of reaction rate constants for the various monomer radical reactions is javascript pdf preview image Generating thumbnail of a pdf using PDF.js - Stack Overflow
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Dec 6, 2016 · Mozilla's PDF.JS is PDF viewer made with HTML5 technologies. It can help your application in custom rendering of PDF files — showing a PDF ... unhindered monomers.) This order of reactivity concisely summarizes the data in Tables 6-3 and 6-4 as well as many homopolymerization data. It is clear that monomers without stabilizing substituents (e.g., vinyl chloride or vinyl acetate) will self-propagate faster than those with stabilizing substituents (e.g., styrene) (Reaction 6-51a versus 6-51c). Copolymerization, on the other hand, will occur primarily between two monomers with stabilizing substituents or between two monomers without stabilizing substituents. The combination of a monomer with a stabilizing substituent and one without (e.g., styrene vinyl acetate) yields a system in which a combination of Reactions 6-51b and 6-51d is required to have facile copolymerization. This does not occur, since Reaction 6-51d is very slow. Thus in the styrene vinyl acetate system copolymerization is not ef cient, since styrene radical is too unreactive to add to the unreactive vinyl acetate monomer. 6-3b-2 Steric Effects javascript pdf preview image Javascript - Previewing PDFs During Upload
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